Guest-induced crystal-to-crystal expansion and contraction of a 3-D porous coordination polymer.

نویسندگان

  • Witold M Bloch
  • Christopher J Sumby
چکیده

A silver(I) 3-D porous coordination polymer (PCP, 1) with a sodalite topology undergoes a remarkable reversible crystal-to-crystal expansion and contraction upon exposure to different solvents. Notably, complete desolvation of 1 also facilitates a transformation to a non-porous 2-D coordination polymer (2).

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عنوان ژورنال:
  • Chemical communications

دوره 48 19  شماره 

صفحات  -

تاریخ انتشار 2012